Inorganic Chemistry: Periodicity Flashcards

Explain trends in the periodic table using atomic structure and bonding. (22 cards)

1
Q

What determines an element’s position in the Periodic Table?

A

Proton number

The number of protons defines the element and its position.

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2
Q

How are elements classified into blocks in the Periodic Table?

A

By highest energy sub-shell

The block corresponds to the type of sub-shell being filled by the outer electrons.

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3
Q

Fill in the blank:

Elements in the _______ block have their outer electrons entering an s sub-shell.

A

s

Groups 1 and 2 are typical examples of s-block elements.

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4
Q

True or False:

The p block occupies the right-hand side of the Periodic Table.

A

True

It includes Groups 13–18 where electrons fill p orbitals.

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5
Q

Which block contains the transition metals?

A

d block

These elements have electrons filling the d sub-shell.

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6
Q

True or False:

The f block contains the lanthanides and actinides.

A

True

These elements involve filling of the f sub-shell.

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7
Q

Fill in the blank:

The block of an element depends on which type of ___-____ is being filled by electrons.

A

sub-shell

Sub-shells include s, p, d and f orbitals.

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8
Q

What block do Group 1 elements belong to?

A

s block

Their outer electron occupies an s orbital.

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9
Q

True or False:

Elements in the same block must have the same number of electrons.

A

False

They share the same type of sub-shell being filled, not the same number of electrons.

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10
Q

What type of sub-shell is being filled in p-block elements?

A

p sub-shell

These sub-shells contain three orbitals.

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11
Q

What general trend is observed in atomic radius across Period 3 from Na to Ar?

A

Decreases

Increasing nuclear charge pulls electrons closer while shielding remains similar.

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12
Q

What happens to first ionisation energy across Period 3 from Na to Ar?

A

Increases

Stronger nuclear attraction makes electrons harder to remove.

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13
Q

Fill in the blank:

Across Period 3, atomic radius decreases because nuclear _______ increases.

A

charge

More protons attract the same outer shell of electrons more strongly.

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14
Q

True or False:

Shielding increases significantly across Period 3.

A

False

Electrons are added to the same shell, so shielding changes little.

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15
Q

Why does atomic radius decrease across Period 3?

A

Greater nuclear attraction

More protons pull the electron cloud closer to the nucleus.

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16
Q

True or False:

The first ionisation energy is the energy required to remove one electron from each atom in one mole of gaseous atoms.

A

True

This definition applies to the first ionisation energy.

17
Q

Fill in the blank:

A higher nuclear charge leads to a _______ first ionisation energy.

A

higher

Electrons are held more strongly by the nucleus.

18
Q

What type of structure explains the high melting points of sodium, magnesium and aluminium?

A

Metallic lattice

Strong metallic bonding requires significant energy to break.

19
Q

True or False:

Silicon has a very high melting point because it forms a giant covalent structure.

A

True

Strong covalent bonds extend throughout the lattice.

20
Q

Why do melting points drop sharply from silicon to phosphorus?

A

Molecular structure

Silicon is macromolecular whereas P4 molecules are held together by weak intermolecular forces.

21
Q

Fill in the blank:

Phosphorus, sulfur and chlorine have relatively low melting points due to _______ intermolecular forces.

A

weak

These substances consist of simple molecular structures.

22
Q

Why does sulfur have a higher melting point than phosphorus?

A

Larger molecules

S8 molecules experience stronger London forces than P4 molecules.